Calculate ferrite content in stainless steel & duplex stainless steel

Importance of Ferrite in Austenitic & Duplex stainless steel welds

A characteristic of austenitic stainless is their susceptibility to hot-short cracking after being welded. This is also called micro-fissuring. This problem is corrected by using electrodes that deposit weld metal containing a small amount of ferrite. Due to this most of the electrodes for welding austenitic stainless steel contains 3 to 10% ferrite even though the same steel base material contains no ferrite. For low-temperature service, the weld metal should have a ferrite content in the range of 4 to 10%.

Similarly, ferrite control is very critical in duplex stainless steel weldments. Duplex stainless steel welds & HAZ that have a high amount of ferrite can have low impact toughness, reduced ductility, and reduced corrosion resistance. Hence, control of ferrite is highly desirable when welding duplex stainless steel.

Ferrite Calculation methods

WRC-1992 Phase diagram ((gives ferrite Number) and ESPY diagram (gives ferrite percentage) are can be used to predict the ferrite content of weld deposit using the chemical composition of the welds. The other phase diagrams such as (SCHAEFFLER or DELONG) which do not count nitrogen and copper amount- can’t be used for duplex stainless steel weldments.

Measurement methods

The determination of the ferrite content in austenitic steels can be made either metallographically by using micro-sections, (destructively) or magneto-inductively (nondestructively) such as the ferritscope (results in F% or FN) or magne-gage (results in FN) directly at the weld. However, in magneto-inductive testing, the reading is a function of the chemical composition of the alloy. Therefore, when dealing with high ferrite content the indicated ferrite content does not correspond to the actual content in the material, since high-alloyed ferrite tends to have a weaker magnetic reaction than the same ferrite content does with a lower alloy potential. For these reasons, the Ferrite number (FN) was introduced for indication of the content of ferrite (EN ISO 8249 and EN ISO 17 655).

The above Ferrite determination methods can’t be used for localized ferrite measurements. For measuring ferrite in a localized area, the Metallographic grid technique is used. The method is performed according to the ASTM E562 standard at a high magnification level usually more than 400X is used for ferrite measurement. Magnification plays an important role in ferrite measurement in the grid method as highlighted in the below figure.

Other Ferrite measurement techniques are also used in the industries. One main type is image analysis ferrite measurements as per ASTM E1245.

Range of Ferrite Content for Duplex Stainless-Steel Welding Qualification:

In Duplex stainless steel weldments & heat-affected zone (HAZ), the Ferrite content shall be within the range given below:

  1. In Weld metal—30% to 65%,
  2. In Heat affected zone or HAZ—40% to 65%,
  3. in the Base metal—40% to 60%.

NOTE 1 Ferrite content below 25% can also be accepted for weld where corrosion test or other related tests can be shown satisfactorily. Welding carried out using Nickel base consumables does not require ferrite content measurements.

NOTE 2 Use the following formula to convert ferrite % to FN:

  1. For 22 % Cr duplex stainless steel, ferrite % = 0.7 × FN;
  2. For 25 % Cr duplex and super duplex stainless steels, ferrite % = 0.65 × FN.

Influence of Elements and Cooling rate on % Ferrite

Fast Cooling — High Ferrite

Slow Cooling — Low Ferrite

Effect of Ferrite & austenite in Duplex Stainless Steel

Metallographic Tests

These tests are rarely called for in specifications but they are commonly used for quality control and during inspection to determine weld soundness, to examine the extent and distribution of non-metallic inclusions in the weld, to check the number and arrangement of runs, to determine the metallurgical structure in the fusion zone and the heat-affected zone and to check the depth of weld penetration.

Samples are obtained from a test weld by sectioning or from a production weld by trepanning. Trepanning means mechanical removal of the weld joint portion in one piece with a special tool, which leaves a recess in the joint which can be easily filled up by welding. From these samples, macro specimens or micro specimens are prepared by suitable etching procedures as follows:

Macro-Specimens in Metallography

If one wants to avoid grinding and polishing of the cross-sectional surface, one can directly place the specimen in boiling 50% solution of hydrochloric acid in water for approximately 30 min. Alternately, one may first grind and smoothen the surface with emery wheel or emery paper and then vigorously rub the surface with a piece of cotton fully wetted with a solution of one part of solid ammonium persulphate in nine parts of water by weight. This rubbing action must be repeated until a clearly defined macrostructure appears on the weld.

After etching, the specimens are washed thoroughly in clear water and wiped dry. They are then immersed in ethyl alcohol, removed and air dried. If a specimen is to be preserved, a coat of thin, clear lacquer may be applied, so that the surface does not rust in storage.

Micro-Specimens in Metallography

:These specimens have to be prepared with a highly polished mirror-like surface and etched with proper chemicals and techniques depending on the type of alloy and the microstructures one is looking for. The procedure of sample preparation and examination is complicated and requires suitable equipment and a trained metallographer. Interpretation of the photomicrographs also demands a sound knowledge of physical metallurgy.

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